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Yui Hirasawa
Ui hugging Yui Yui Hirasawa is the older sister of Ui Hirasawa, although Ui acts more like the "older sister" of Yui, as she is more responsible and mature enough to take care of her older sister. Yui is quite happy to have Ui as a sister and loves her very much. This is proven when she decides to make a meal for Ui when she got sick taking care of her despite her lack of cooking skills compared to Ui. Yui even dedicates one of the very first songs that she writes to Ui.
Jun Suzuki
Ui and jun Jun and Ui have been friends since primary school. They also went to the same junior high school and spend a lot of time together. In their first year, Ui tried to persuade Jun to join the Light Music Club, but Jun declined and instead joined the Jazz Club. In their third year, after the senior members of the Light Music Club had left for university, Jun and Ui together finally joined Azusa in building the new Light Music Club (Wakaba Girls) and recruiting other students from their school to get involved.
Azusa Nakano
Ui and azusa Azusa and Ui have been good friends since their first year of high school. At that time, Ui introduced Azusa to the Light Music Club, accompanying her to their live performance at the freshman reception and persuading her to join the club.

After that event, they became good friends. When Azusa worried about new club members for the new Light Music Club, Ui and Jun gave her confidence by joining the club and together and trying to persuade other students to get involved. 

Nodoka Manabe
Nodoka and Ui Nodoka Manabe and Ui are childhood friends because Nodoka often visited Ui's older sister Yui at home. Nodoka likes Ui very much and knows about her responsible character, often teasing Yui about it; for example, Nodoka joked that the sisters were born in the wrong order, which refers to the fact that Ui, the younger sister, is much more mature than the older sister, Yui.

Despite feeling a bit uneasy about Ui's habit of hugging her at home, Nodoka still lets it happen without much of a problem.

Nevertheless, Nodoka still insists to be addressed by Ui properly at school as an upperclassman.

Ritsu Tainaka
Ritsu and Ui Ritsu and Ui get along well. Ui respects Ritsu as a formidable upperclassmen despite her immature nature and is thankful to her for being such a good friend with her sister Yui. Ritsu is always amazed by Ui's housekeeping skills and told Yui more than once that she is envious and "also wants an Ui at home". At one time the two played video games together and Ui beat Ritsu in-game, much to the grief of the latter.